To run reports on current salesperson and B2B users, start by going to manage users in the admin tab.

Use the filters on the left hand side to filter down to a specific user type.  Hit apply.

Use the filters to select only approved or unapproved users.  Hit apply.

This will pull up a list of all users that meet the criteria selected including account number if the user is a customer, salesperson ID for customer and salespseron users and a list of roles.  This can be exported to excel.